Lo intentéesta solución con Elmah.XmlFileErrorLog pero obtengo la siguiente excepción

System.ArgumentNullException was unhandled by user code
  Message="Value cannot be null.\r\nParameter name: context"
  Source="Elmah"
  ParamName="context"
  StackTrace:
       at Elmah.ErrorSignal.FromContext(HttpContext context) in c:\builds\ELMAH\src\Elmah\ErrorSignal.cs:line 67
       at Elmah.ErrorSignal.FromCurrentContext() in c:\builds\ELMAH\src\Elmah\ErrorSignal.cs:line 61
       at ElmahHttpErrorHandler.ProvideFault(Exception error, MessageVersion version, Message& fault) in c:\Myapplication\App_Code\Util\ElmahHttpErrorHandler.cs:line 19
       at System.ServiceModel.Dispatcher.ErrorBehavior.ProvideFault(Exception e, FaultConverter faultConverter, ErrorHandlerFaultInfo& faultInfo)
       at System.ServiceModel.Dispatcher.ErrorBehavior.ProvideMessageFaultCore(MessageRpc& rpc)
       at System.ServiceModel.Dispatcher.ImmutableDispatchRuntime.ProcessMessageCleanup(MessageRpc& rpc)
  InnerException: 

Archivo web.Config

<configSections>
    <section name="loggingConfiguration" type="Microsoft.Practices.EnterpriseLibrary.Logging.Configuration.LoggingSettings, Microsoft.Practices.EnterpriseLibrary.Logging, Version=4.1.0.0, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
    <section name="exceptionHandling" type="Microsoft.Practices.EnterpriseLibrary.ExceptionHandling.Configuration.ExceptionHandlingSettings, Microsoft.Practices.EnterpriseLibrary.ExceptionHandling, Version=4.1.0.0, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
    <section name="dataConfiguration" type="Microsoft.Practices.EnterpriseLibrary.Data.Configuration.DatabaseSettings, Microsoft.Practices.EnterpriseLibrary.Data, Version=4.1.0.0, Culture=neutral, PublicKeyToken=31bf3856ad364e35"/>
    <sectionGroup name="system.web.extensions" type="System.Web.Configuration.SystemWebExtensionsSectionGroup, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35">
        <sectionGroup name="scripting" type="System.Web.Configuration.ScriptingSectionGroup, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35">
            <section name="scriptResourceHandler" type="System.Web.Configuration.ScriptingScriptResourceHandlerSection, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" requirePermission="false" allowDefinition="MachineToApplication"/>
            <sectionGroup name="webServices" type="System.Web.Configuration.ScriptingWebServicesSectionGroup, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35">
                <section name="jsonSerialization" type="System.Web.Configuration.ScriptingJsonSerializationSection, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" requirePermission="false" allowDefinition="Everywhere"/>
                <section name="profileService" type="System.Web.Configuration.ScriptingProfileServiceSection, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" requirePermission="false" allowDefinition="MachineToApplication"/>
                <section name="authenticationService" type="System.Web.Configuration.ScriptingAuthenticationServiceSection, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" requirePermission="false" allowDefinition="MachineToApplication"/>
                <section name="roleService" type="System.Web.Configuration.ScriptingRoleServiceSection, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" requirePermission="false" allowDefinition="MachineToApplication"/>
            </sectionGroup>
        </sectionGroup>
    </sectionGroup>
  <sectionGroup name="elmah">
    <section name="security" requirePermission="false" type="Elmah.SecuritySectionHandler, Elmah" />
    <section name="errorLog" requirePermission="false" type="Elmah.ErrorLogSectionHandler, Elmah" />
    <section name="errorMail" requirePermission="false" type="Elmah.ErrorMailSectionHandler, Elmah" />
    <section name="errorFilter" requirePermission="false" type="Elmah.ErrorFilterSectionHandler, Elmah" />
  </sectionGroup>
</configSections>
<httpHandlers>
  <add verb="POST,GET,HEAD" path="elmah.axd" type="Elmah.ErrorLogPageFactory, Elmah" />
  <remove verb="*" path="*.asmx"/>
    <add verb="*" path="*.asmx" validate="false" type="System.Web.Script.Services.ScriptHandlerFactory, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35"/>
    <add verb="*" path="*_AppService.axd" validate="false" type="System.Web.Script.Services.ScriptHandlerFactory, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35"/>
    <add verb="GET,HEAD" path="ScriptResource.axd" type="System.Web.Handlers.ScriptResourceHandler, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35" validate="false"/>
</httpHandlers>
<httpModules>
    <add name="ScriptModule" type="System.Web.Handlers.ScriptModule, System.Web.Extensions, Version=3.5.0.0, Culture=neutral, PublicKeyToken=31BF3856AD364E35"/>
  <add name="ErrorLog" type="Elmah.ErrorLogModule, Elmah" />
</httpModules>
...

<elmah>
  <errorLog type="Elmah.XmlFileErrorLog, Elmah" logPath="~/App_Data" />
  <security allowRemoteAccess="1" />
</elmah>

Estoy usando Windows 7. ¿Puede haber algún problema relacionado con él?

ACTUALIZAR Nota: estoy ejecutando el servicio WCF en ASP.NET. es decir, agregué el proyecto del Servicio WCF a la solución mediante Agregar nuevo sitio web y luego seleccioné la plantilla del Servicio WCF. Actualmente lo estoy ejecutando desde IDE. Sin embargo, alojarlo en IIS tampoco ayudó.