Учти это:

#include <iostream>
#include <map>
#include <string>
#include <boost/assign/list_of.hpp>
using boost::assign::map_list_of;

const std::map<int, std::map<int, char> > test = map_list_of
    (100, map_list_of
        (1, 'a')
        (2, 'b')
    )
    (101, map_list_of
        (1, 'c')
        (2, 'd')
    )
;

int main()
{
    std::cout << test.find(101)->second.find(2)->second << "\n";
}

Я хотел, чтобы результат был программой, которая при выполнении выводитd.

Вместо,Я понял:

$ clang++ -std=c++03 -O2 -Wall -pedantic -pthread main.cpp

In file included from main.cpp:1:
In file included from /usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/iostream:39:
In file included from /usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/ostream:38:
In file included from /usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/ios:40:
In file included from /usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/char_traits.h:39:
In file included from /usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_algobase.h:64:
/usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_pair.h:119:22: error: call to constructor of 'std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > >' is ambiguous
        : first(__p.first), second(__p.second) { }
                            ^      ~~~~~~~~~~
/usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_tree.h:1843:29: note: in instantiation of function template specialization 'std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > >::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > >' requested here
          _M_insert_unique_(end(), *__first);
                                   ^
/usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_map.h:255:16: note: in instantiation of function template specialization 'std::_Rb_tree<int, std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > >, std::_Select1st<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > >, std::less<int>, std::allocator<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > > >::_M_insert_unique<std::_Deque_iterator<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > >, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > &, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > *> >' requested here
        { _M_t._M_insert_unique(__first, __last); }
               ^
/usr/local/include/boost/assign/list_of.hpp:163:20: note: in instantiation of function template specialization 'std::map<int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > >, std::less<int>, std::allocator<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > > >::map<std::_Deque_iterator<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > >, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > &, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > *> >' requested here
            return Container( begin(), end() );
                   ^
/usr/local/include/boost/assign/list_of.hpp:142:20: note: in instantiation of function template specialization 'boost::assign_detail::converter<boost::assign_detail::generic_list<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > >, std::_Deque_iterator<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > >, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > &, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > *> >::convert<std::map<int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > >, std::less<int>, std::allocator<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > > > >' requested here
            return convert<Container>( c, tag_type() );
                   ^
/usr/local/include/boost/assign/list_of.hpp:436:49: note: in instantiation of function template specialization 'boost::assign_detail::converter<boost::assign_detail::generic_list<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > >, std::_Deque_iterator<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > >, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > &, std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > *> >::convert_to_container<std::map<int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > >, std::less<int>, std::allocator<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > > > >' requested here
            return this-> BOOST_NESTED_TEMPLATE convert_to_container<Container>();
                                                ^
main.cpp:7:50: note: in instantiation of function template specialization 'boost::assign_detail::generic_list<std::pair<int, boost::assign_detail::generic_list<std::pair<int, char> > > >::operator map<std::map<int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > >, std::less<int>, std::allocator<std::pair<const int, std::map<int, char, std::less<int>, std::allocator<std::pair<const int, char> > > > > > >' requested here
const std::map<int, std::map<int, char> > test = map_list_of
                                                 ^
/usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_map.h:171:7: note: candidate constructor
      map(const _Compare& __comp,
      ^
/usr/local/bin/../lib/gcc/x86_64-unknown-linux-gnu/4.9.2/../../../../include/c++/4.9.2/bits/stl_map.h:182:7: note: candidate constructor
      map(const map& __x)
      ^
1 error generated.

(аналогичные результаты по GCC)

Как я могу решить это?

Я получаю похожую ошибку, даже если я используюstd::map<int, char>(map_list_of(...)) вместоmap_list_of(...) для тех внутренних карт.